| Conjugate variables of thermodynamics |
|
|---|---|
| Pressure | Volume |
| (Stress) | (Strain) |
| Temperature | Entropy |
| Chemical potential | Particle number |
The particlenumber (or number of particles) of a thermodynamic system, conventionally indicated with the letter N, is the number of constituent particles in that system.[1] The particle number is a fundamental parameter in thermodynamics which is conjugate to the chemical potential. Unlike most physical quantities, particle number is a dimensionless quantity. It is an extensive parameter, as it is directly proportional to the size of the system under consideration, and thus meaningful only for closed systems.
A constituent particle is one that cannot be broken into smaller pieces at the scale of energy k·T involved in the process (where k is the Boltzmann constant and T is the temperature). For example, for a thermodynamic system consisting of a piston containing water vapour, the particle number is the number of water molecules in the system. The meaning of constituent particle, and thereby of particle number, is thus temperature-dependent.
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The concept of particle number has a main role in theoretical considerations. In situations where the actual particle number of a given thermodynamical system needs to be determined, mainly in chemistry, it is not practically possible to measure it directly by counting the particles. If the material is homogeneous and has a known amount of substance n expressed in moles, the particle number N can be found by the relation
where NA is the Avogadro constant.[1]
A related intensive system parameter is given by the particle number density, obtained by dividing the particle number of a system by its volume. This parameter is often denoted by a lower-case letter n.
In quantum mechanical processes the total number of particles may not be preserved. The concept is therefore generalized to the particle number operator, that is, the observable that counts the number of constituent particles.[2] In quantum field theory, the particle number operator (see Fock state) is conjugate to the phase of the classical wave (see coherent state).
One measure of air pollution used in air quality standards is the atmospheric concentration of particulate matter. This measure is also sometimes referred to as the "particle number", although it is usually expressed in μg/m3 (micrograms per cubic metre).